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建筑石膏与胶凝材料
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不同形貌水化硅酸钙的制备及其对水泥水化性能

作者:余林岑1,王伟山2,3,郑柏存1

关键字:不同,形貌,水化,硅,酸钙,的,制备,及其,对,

 
(1.华东理工大学体育新材料研发中心,上海  200237;2.上海三瑞高分子材料股份有限公司,上海  200231;
3.上海建筑外加剂工程技术研究中心,上海  200232)
摘要:采用沉淀法制备形貌分别为类纤维状、类球形堆叠状及团聚锡箔状的水化硅酸钙(C-S-H),并探究了不同形貌C-S-H对水泥水化产物形貌及水泥性能的影响。结果表明:不同形貌的C-S-H对水泥浆体的微观形貌有调控作用;C-S-H能有效缩短凝结时间,加快水泥水化速度,并提高水泥浆体的早期强度,其中纤维状的C-S-H分散性最好,对水泥性能的提高效果最为显著。
关键词:水化硅酸钙(C-S-H);形貌;水泥水化;早期强度
中图分类号:TU528.04        文献标识码:A        文章编号:1001-702X(2018)10-0035-04
 
The preparation of calcium silicate hydrate(C-S-H) with different morphology and the effect on 
hydration properties of cement
  YU Lincen1,WANG Weishan2,3,ZHENG Baicun1
(1.East China University of Science and Technology,Advanced Sport Material R & D Center,Shanghai 200237,China;
2.Shanghai Sunrise Polymer Co. Ltd.,Shanghai 200231,China;3.CAERC,Shanghai 200232,China)
Abstract:Calcium silicate hydrate(C-S-H) with different morphology was synthesized by precipitation method. There are three different types of morphology:the class fibrous,the spherical stacked and reunion foil. And the effect of different morphology of C-S-H on morphology of cement hydrated productsand cement performance was studied. The results show that C-S-H with different morphology can regulate the morphology of cement hydration products.Adding C-S-H can effectively shorten the setting time,speed up the cement hydration and improve the early strength of cement paste. The morphology of fibrous C-S-H with the best dispersion have the most significant effect on the cement performance.
Key words:calcium silicate(C-S-H),morphology,cement hydration,early strength